6H,13H-5,12:7,14-Dimethanodinaphtho[2,3-d:2,3-i][1,3,6,8]tetraazecine
نویسندگان
چکیده
In the title compound, C(24)H(20)N(4), obtained through the condensation of naphthalene-2,3-diamine with formaldehyde in methanol, the mol-ecule is located on a special position of site symmetry -4. Due to symmetry considerations, the aromatic rings are strictly perpendicular to each other. In the crystal, mol-ecules are linked by pairs of C-H⋯π inter-actions into columns along [110].
منابع مشابه
2,9-Dichloro-6H,13H-5:12,7:14-dimethanodibenzo[d,i][1,3,6,8]tetraazecine
The title compound, C(16)H(14)Cl(2)N(4), is isomorphous with 2,9-dimethyl-6H,13H-5:12,7:14-dimethano-dibenzo[d,i]-[1,3,6,8]tetra-azecine [Rivera et al. (2009 ▶). Acta Cryst. E65, o2553] and has twofold symmetry, with two carbon atoms located on a twofold axis. Only van der Waals forces occur between molecules in the crystal. In the isomorphous compound the crystal structure is stabilized by wea...
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In the title structure, C(18)H(20)N(4), the aromatic rings are almost orthogonal [81.6 (2)°]. The mol-ecule has symmetry 2 since it is situated on a crystallographic twofold axis. There are only weak inter-molecular inter-actions present in the structure, notably C-H⋯π-electron ring inter-actions. The (1)H and (13)C NMR spectra are in accordance with the X-ray structure analysis.
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Two new 5,12-disubstituted 2,3-di-ethyl-naphtho-[2,3-g]quinoxaline-6,11-dione compounds were readily synthesized from the commercial dye quinizarin. For 2,3-diethyl-5,12-di-hydroxy-naphtho-[2,3-g]quinoxaline-6,11-dione, (II), C20H16N2O4, the mol-ecule displays a near planar conformation and both hy-droxy groups participate in intra-molecular O-H⋯O(carbon-yl) hydrogen bonds. In the crystal, π-π ...
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012